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Synthesis and stereochemical analysis of the triangular cobalt-dinickel clusters, (.eta.5-C5H5-nMen)CoNi2(.eta.5-C5H5)2(.mu.3-CO)2 (where n = 0, 1, 5): direct evidence for the antibonding trimetal character of the unpaired electron in the Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2 and resulting geometrical effects upon formal oxidation by replacement of a nickel with a cobalt atom

Synthesis and stereochemical analysis of the triangular cobalt-dinickel clusters, (.eta.5-C5H5-nMen)CoNi2(.eta.5-C5H5)2(.mu.3-CO)2 (where n = 0, 1, 5): direct evidence for the antibonding trimetal character of the unpaired electron in the Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2 and resulting geometrical effects upon formal oxidation by replacement of a nickel with a cobalt atom

Byers, Lance R.; Uchtman, Vernon A.; Dahl, Lawrence F.
  • 期刊名称Journal of the American Chemical Society
  • 作者Byers, Lance R.; Uchtman, Vernon A.; Dahl, Lawrence F.
  • 卷第103卷
  • 期第8期
  • 印刷ISSN0002-7863
  • 文件大小1470.98KB
  • 发表时间1981-04
  • DOI10.1021/ja00398a011
  • 页码1942-1951
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