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Head to head acetylene coupling at a heterobimetallic center to give a rhodacyclopentadieneiron unit. Syntheses and x-ray crystal structures of (tert-Bu2PH)(CO)2Fe(.mu.-CO)(.mu.-tert-Bu2P)Rh(COD)(FeRh), (CO)2Fe(.mu.-tert-Bu2P)(.mu.-.eta.4-C4H2(Ph)2)Rh(HCCPh)(FeRh), and Rh2Fe(CO)3(tert-Bu2PH)(.mu.-CO)2(.mu.-tert-Bu2P)2

Head to head acetylene coupling at a heterobimetallic center to give a rhodacyclopentadieneiron unit. Syntheses and x-ray crystal structures of (tert-Bu2PH)(CO)2Fe(.mu.-CO)(.mu.-tert-Bu2P)Rh(COD)(FeRh), (CO)2Fe(.mu.-tert-Bu2P)(.mu.-.eta.4-C4H2(Ph)2)Rh(HCCPh)(FeRh), and Rh2Fe(CO)3(tert-Bu2PH)(.mu.-CO)2(.mu.-tert-Bu2P)2

Arif, Atta M.; Chandler, Don J.; Jones, Richard A.
  • 期刊名称Organometallics
  • 作者Arif, Atta M.; Chandler, Don J.; Jones, Richard A.
  • 卷第6卷
  • 期第3期
  • 印刷ISSN0276-7333
  • 电子ISSN1520-6041
  • 文件大小949.86KB
  • 发表时间1987-03
  • DOI10.1021/om00146a012
  • 页码506-512
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