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ChemInform Abstract: Photoinduced Molecular Transformations. Part 155. General Synthesis of Macrocyclic Ketones (VI) Based on a Ring Expansion Involving a Selective β-Scission of Alkoxyl Radicals, Its Application to a New Synthesis of (.+-.)-Isocaryophyllene (XIV) and (.+-.)- Caryophyllene (XV), and a Conformational Analysis of the Two Sesquiterpenes and the Radical Intermediate in the Synthesis by MM3 Calculations.

ChemInform Abstract: Photoinduced Molecular Transformations. Part 155. General Synthesis of Macrocyclic Ketones (VI) Based on a Ring Expansion Involving a Selective β-Scission of Alkoxyl Radicals, Its Application to a New Synthesis of (.+-.)-Isocaryophyllene (XIV) and (.+-.)- Caryophyllene (XV), and a Conformational Analysis of the Two Sesquiterpenes and the Radical Intermediate in the Synthesis by MM3 Calculations.

H. SUGINOME; T. KONDOH; C. GOGONEA; V. SINGH; H. GOTO; E. OSAWA
  • 作者H. SUGINOME; T. KONDOH; C. GOGONEA; V. SINGH; H. GOTO; E. OSAWA
  • 卷第26卷
  • 期第25期
  • 印刷ISSN0931-7597
  • 电子ISSN1522-2667
  • 文件大小42.68KB
  • 发表时间1995
  • DOI10.1002/chin.199525193
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