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Photoinduced molecular transformations. Part 155. General synthesis of macrocyclic ketones based on a ring expansion involving a selective ?-scission of alkoxyl radicals, its application to a new synthesis of (�)-isocaryophyllene and (�)-caryophyllene, and a conformational analysis of the two sesquiterpenes and the radical intermediate in the synthesis by MM3 calculations

Photoinduced molecular transformations. Part 155. General synthesis of macrocyclic ketones based on a ring expansion involving a selective ?-scission of alkoxyl radicals, its application to a new synthesis of (�)-isocaryophyllene and (�)-caryophyllene, and a conformational analysis of the two sesquiterpenes and the radical intermediate in the synthesis by MM3 calculations

Suginome, Hiroshi; Kondoh, Takahiko; Gogonea, Camelia; Singh, Vishwakarma; Got?, Hitoshi; ?sawa, Eiji
  • 期刊名称Journal of the Chemical Society, Perkin Transactions 1
  • 作者Suginome, Hiroshi; Kondoh, Takahiko; Gogonea, Camelia; Singh, Vishwakarma; Got?, Hitoshi; ?sawa, Eiji
  • 期第1期
  • 印刷ISSN0300-922X
  • 电子ISSN1364-5463
  • 文件大小1715.37KB
  • 发表时间1995
  • DOI10.1039/p19950000069
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